By F. G. A. & West, Robert (editors) Stone
This commonly acclaimed serial comprises authoritative experiences that deal with all facets of organometallic chemistry, a box which has accelerated significantly because the ebook of quantity 1 in 1964. just about all branchesof chemistry now interface with organometallic chemistry-the learn of compounds containing carbon-metal bonds. Organometallic compounds diversity from species which are so reactive that they just have a temporary lifestyles at ambient temperatures to these thatare thermally very strong. they're used broadly within the synthesis of precious compounds on either small and massive scales. business tactics concerning plastics, polymers, digital fabrics, and prescription drugs all rely on advances in organometallic chemistry
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Extra resources for Advances in Organometallic Chemistry: Volume 2
98 VI. Mean Bond Dissociation Energies of Metal-Carbon Bonds . 100 VII. Metal-Carbon Bond Dissociation Energies . . . . 107 VII1. Redistribution Reactions of Metal Alkyls and Metal Halides . 108 IX. Intrinsic Metal-Carbon Bond Energies . . . References . . . . . . . . . 110 I INTRODUCTION Reliable information on the strengths of metal-to-carbon bonds is still meager, despite notable additions made within the past decade. This unsatisfactory state of affairs has been caused by the diffidence of thermochemists to tackle organometallic compounds until recently, and by failings of conventional thermochemical techniques when applied to this class of compound.
G. N. Schrauzer and H. Thyret, Theoret. Chim. Acta 1, 172 (1963). 62. L. E. Orgel, Trans. 52, 1172 (1956). 63. H. Thyret, Doctoral Thesis, University of Munich, Munich, 1962. 64. G. N. Schrauzer and H. Thyret, Angew. Chem. 75,641 (1963). 65. W. Reppe and W. J. Schweckendieck, Ann. Chem. 560, 104 (1948). 66. W. Hubel and C. Hoogzand in “Organic Syntheses via Metal Carbonyls” (I. Wender and P. ). J. Wiley and Sons, New York. To be published. 67. L. S. Meriwether, E. C. Colthup, G. W. Kennedy, and R.
Dietrich and R. Uttech, Naturzuissemchaften 50, 613 (1963). 104. R. E. Benson and R. V. ,J. A m . Chem. 81,4247 (1959). 105. J. K. Williams and R. E. Benson,?. A m . Chem. 84, 1257 (1962). 106. R. E. Benson and R. V. Lindsey, J r . , r . A m . Chem. SOC. 81,4250 (1959). 107. R. E. Benson. R. V. , and B. C. Anderson,?. A m . Chem. 81,4253 (1959). T h e Strengths of Metul-to- Curbon Bonds H. A. SKINNER Chemistry Deportment, University o f Monchester, Monchester, England I. Introduction . . . .